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When [tex]$1.00 \, \text{g}[tex]$[/tex] of solid [tex]$[/tex]K[tex]$[/tex] was added to water, about [tex]$[/tex]4610 \, \text{J}$[/tex] of energy are released.

What is the enthalpy of the reaction?
[tex]
\Delta H_{\text{rxn}} = [?] \, \text{kJ/mol}
[/tex]



Answer :

To determine the enthalpy of the reaction (ΔH_rxn), we need to follow a series of steps involving conversions and calculations. Here's a detailed step-by-step solution:

1. Know the Given Values:
- Energy released, \( Q \) = 4610 Joules (J)
- Mass of potassium, \( m \) = 1.00 grams (g)
- Molar mass of potassium, \( M_{\mathrm{K}} \) = 39.10 g/mol

2. Calculate the Number of Moles of Potassium:
The number of moles of potassium, \( n \), can be calculated using the formula:
[tex]\[ n = \frac{m}{M_{\mathrm{K}}} \][/tex]
Substituting the given values:
[tex]\[ n = \frac{1.00 \, \text{g}}{39.10 \, \text{g/mol}} \approx 0.02557544757033248 \, \text{mol} \][/tex]

3. Convert the Energy Released to Kilojoules:
Since enthalpy (ΔH_rxn) is usually given in kilojoules per mole, we need to convert the energy from joules to kilojoules:
[tex]\[ Q_{\mathrm{kJ}} = \frac{Q}{1000} = \frac{4610 \, \text{J}}{1000} = 4.610 \, \text{kJ} \][/tex]

4. Calculate the Enthalpy Change per Mole (ΔH_rxn):
The enthalpy change of the reaction (ΔH_rxn) can be calculated using the formula:
[tex]\[ \Delta H_{\mathrm{rxn}} = \frac{Q_{\mathrm{kJ}}}{n} \][/tex]
Substituting the values we have:
[tex]\[ \Delta H_{\mathrm{rxn}} = \frac{4.610 \, \text{kJ}}{0.02557544757033248 \, \text{mol}} \approx 180.251 \, \text{kJ/mol} \][/tex]

Therefore, the enthalpy of the reaction, [tex]\( \Delta H_{\mathrm{rxn}} \)[/tex], is approximately 180.251 kJ/mol.

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